A Stable Alkylated Cobalt Catalyst for Photocatalytic H <sub>2</sub> Generation in Liposomes
نویسندگان
چکیده
Artificial photosynthesis: A novel amphiphilic cobalt(II) polypyridyl complex (CoC12) and an ruthenium photosensitiser (RuC12) were immobilised on liposomes to perform photocatalytic H2 generation in the presence of ascorbate (Hasc?) tris-2-carboxyethylphosphine hydrochloride (TCEP) as sacrificial electron donors. In such conditions, CoC12 was found be photostable, while optimised turnover number (161) limited by decomposition ruthenium-based photosensitiser.
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ژورنال
عنوان ژورنال: Chemcatchem
سال: 2022
ISSN: ['1867-3899', '1867-3880']
DOI: https://doi.org/10.1002/cctc.202200484